Podcasts are not a good medium for actually learning anything. Almost all the things you might learn from tech podcasts could be summarized in a paragraph.
This applies to a lot of technical books too.
This one is not really a technical podcast. But "how i built this" by Guy Raz on PBS was a great set of stories on building a business.
https://itunes.apple.com/us/podcast/hypergrowth-podcast/id1368462653?mt=2
Jocko podcast
Syntax is good, it's on Spotify